Mr. and Mrs. Smith (2005)

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John and Jane Smith are a bored upper middle class married couple surprised to learn that they are assassins belonging to competing agencies, and that they have been assigned to kill each other. The couple has been married for "five or six" years, but their marriage is suffering. In reality, John and Jane are both skilled field operatives working for different contract killing firms, both among the best in their field, each concealing their true profession from the other.